There are two separate issues here.
For Daw.apple.com, the name alone is not enough to identify what the entry represents.
Open Passwords, select Daw.apple.com, and check the username and type of credential shown.
Do not share the actual password. If you confirm that you no longer need the entry, select Edit >> Delete Password.
This removes the saved password or passkey from Passwords; it does not delete the underlying account. Apple: Find, change, or delete saved passwords and passkeys on Mac
The password you enter when Touch ID is not available is your Mac login password.
Touch ID does not replace that password, and macOS requires the password in certain situations, including after a restart.
Your Apple Account password is separate, so the two passwords can be different. Apple: Use Touch ID on Mac
To change your Apple Account password, go to Apple menu >> System Settings >> your name >> Sign-In & Security >> Change Password.
The Passwords app can contain a saved Apple Account related credential, but changing or viewing that saved entry does not establish or change your current Apple Account password.
The actual Apple Account password is changed through your Apple Account settings. Apple: Change your Apple Account password
If you want to determine exactly what Daw.apple.com is before deleting it, tell us what username and type of credential are shown in that entry, without giving us the password.